Electrophoretic Study of d-Block Metal Ions on Plain and Tri-n-Butylamine (TBA) Impregnated Titanium (IV) Tungstate Layers

  • Sd Sharma School of Sciences, IFTM University, Moradabad, Uttar Pradesh, India
  • Mridul Gupta J.S. Hindu college, Amroha, JP Nagar, Uttar Pradesh, India
Keywords: RPTLE-reversed phase thin layer electrophresis, TBA-tri n butylamine, OA-oxalic acid, TA-tartaric acid,, CA-citric acid, Kd-distribution coefficient, Ka- ionization constant, Mi-migration on untreated layers-migration on impregnated layers

Abstract

RPTLE of ninteen d block metal ion studied on TBA impregnated titanium(IV)tungstate layer in nine solvent system among them three are complex forming acids OA,TA, CA to study the effect of complexation on migration. Electrophoretic migration also correlated with Ionc potential,Kd of metal ions and Ka of acids,pH of electrolytes.The spots are well defined in RPTLE and Mi is positive

References

[1] Consden, R., Gorden, A.H and Martin, A.J.P. (1946) J.Biochem, 40, 33. ; Kunkel, H.G and Wallenius, G, (1955) Sciences, 122, 288; Smithies, O, (1955) J. Biochem, 61, 629; Groulade.J, Fine, J.M and Ollivier.C, (1961) Nature, 191, 72; Marti, H.R. (1961) Experentia, 17, 235; Honegger. C. G, Helv. (1961) Chim. Acta, 44, 173; Pastuska, G and Trinks. H. (1961) Chemiker Zig 85, 535; Vahvasel Ko. (1962) E, Nature, 193, 474; Hollender, A., Scand. (1962) J.Clin. Lab. Invest 14, 104; Raymond. S and Marumi.N. (1962) Anal. Biochem. 3, 23; Pastuska, G and Trinks, H. (1962) Chemiker Zig, 86, 135.
[2] Dobici. F and Grassini. G. (1963) J. Chromatogr. 10, 98http://dx.doi.org/10.1016/S0021-9673(01)92278-2
[3] Frache. R and Dadone. A. (1973) Chromatographia. 6, 430http://dx.doi.org/10.1007/BF02281022
[4] Frache. R and Dadone. A. (1973) Chromatographia. 6, 266http://dx.doi.org/10.1007/BF02281022
[5] Groulade. J, Fine. J.M and Ollivier. C. (1961) Nature, 191, 72http://dx.doi.org/10.1038/191072a0
[6] Hollender. A, Scand. (1962) J. Clin. Lab. Invest, 14, 104
[7] Honegger. C.G, Helv. (1961) Chim. Acta, 44, 173
[8] Lurie. J. (1975) Handbook of Analytical Chemistry, Mir Publishers, Mascow p 30.
[9] Makrova, T.P and Stapnov, A.V. (1972) Zh. Ana. Khim, 26(9), 1823; Sharma, S.D and Misra. S. (1991) J. Liq. Chromatogr. 14 (181), 1453
[10] Makrova. T.P and Stapnov. A. V. (1971) Zh. Anal. Khim. 26(9), 1823
[11] Martin. H.R. (1961) Experentia, 17, 235 http://dx.doi.org/10.1007/BF02160641
[12] Moghissi. A. (1964) Anal. Chim. Acta. 80, 91http://dx.doi.org/10.1016/S0003-2670(00)88690-0
[13] Murray. D.J and Fuerstnu. M.C. (1968) J. Inorg. Nucl. Chem., 30, 3325http://dx.doi.org/10.1016/0022-1902(68)80129-0
[14] Pastuska. G and Trinks. H. (1961) Chemiker Ztg. 85, 535
[15] Pastuska. G and Trinks. H. (1962) Chemiker Ztg. 86, 135
[16] Qureshi. M, Kumar. R and Rathore. H.S. (1970) J. Chem. Soc. 272http://dx.doi.org/10.1039/j19700000272
[17] Qureshi. M, Varshney. K.G and Fatima. N. (1978) Sepr. Sci and Technol., 13(4), 321.
[18] Qureshi. M, Zehra. N, Nabi. S.A and Kumar.V. (1973) Talanta, 20, 609 http://dx.doi.org/10.1016/0039-9140(73)80111-0
[19] Raymond. S and Masumi. N. (1962) Anal. Biochem. 3, 23http://dx.doi.org/10.1016/0003-2697(62)90040-4
[20] Sharma. S.D and Gupta. Rachna. (2001) J. Ind. Chem. Soc. 78, 301
[21] Sharma. S.D and Misra. S. (1991) J. Liq. Chromatogr. 14(8), 1453http://dx.doi.org/10.1080/01483919108049627
[22] Sharma. S.D and Sharma. C. (2000) J. Planar Chromatogr. 13 93
[23] Sharma. S.D and Sharma. S.C. (1999) J. Chromatogr. 841, 263http://dx.doi.org/10.1016/S0021-9673(99)00293-9
[24] Sharma. S.D, Misra. S and Agarwal. R. (1995) Chem. Environ. Res. 4 (1 & 2), 111.
[25] Sharma. S.D, Misra. S and Sharma.S.C. (1998) J. Ind. Chem. Soc. 75, 81
[26] Sharma. S.D, Sharma. S.C and Sharma. C. (2001) J. Planar Chromatogr. 14, 16
[27] Sharma. S.D, Sharma. S.C and Sharma.C. (1999) J. Planar Chromatogr, 12, 440
[28] Shimizu. T, Tanake. T and Kobayashi. M, J. Planar Chromatogr., 8, 469
[29] Shimizu. T, Tanake.T and Toyoshima .Y. (1994) J. Planar Chromatogr. 8, 152
[30] Smithies. O. (1955) J .Biochem. 61, 629
[31] Toube. H. (1952) Chem. Rev., 50, 69 http://dx.doi.org/10.1021/cr60155a003
[32] Vahvaselko. E. (1962) Nature, 193, 474 http://dx.doi.org/10.1038/193474a0
Published
2015-03-30
How to Cite
Sd Sharma, & Mridul Gupta. (2015). Electrophoretic Study of d-Block Metal Ions on Plain and Tri-n-Butylamine (TBA) Impregnated Titanium (IV) Tungstate Layers. Journal of Chemistry, Environmental Sciences and Its Applications, 1(2), 97-109. Retrieved from https://jce.chitkara.edu.in/index.php/jce/article/view/58
Section
Articles