Electrophoretic Study of d-Block Metal Ions on Plain and Tri-n-Butylamine (TBA) Impregnated Titanium (IV) Tungstate Layers

  • Sd Sharma School of Sciences, IFTM University, Moradabad, Uttar Pradesh, India
  • Mridul Gupta J.S. Hindu college, Amroha, JP Nagar, Uttar Pradesh, India
Keywords: RPTLE-reversed phase thin layer electrophresis, TBA-tri n butylamine, OA-oxalic acid, TA-tartaric acid,, CA-citric acid, Kd-distribution coefficient, Ka- ionization constant, Mi-migration on untreated layers-migration on impregnated layers

Abstract

RPTLE of ninteen d block metal ion studied on TBA impregnated titanium(IV)tungstate layer in nine solvent system among them three are complex forming acids OA,TA, CA to study the effect of complexation on migration. Electrophoretic migration also correlated with Ionc potential,Kd of metal ions and Ka of acids,pH of electrolytes.The spots are well defined in RPTLE and Mi is positive

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References

Consden, R., Gorden, A.H and Martin, A.J.P. (1946) J.Biochem, 40, 33. ; Kunkel, H.G and Wallenius, G, (1955) Sciences, 122, 288; Smithies, O, (1955) J. Biochem, 61, 629; Groulade.J, Fine, J.M and Ollivier.C, (1961) Nature, 191, 72; Marti, H.R. (1961) Experentia, 17, 235; Honegger. C. G, Helv. (1961) Chim. Acta, 44, 173; Pastuska, G and Trinks. H. (1961) Chemiker Zig 85, 535; Vahvasel Ko. (1962) E, Nature, 193, 474; Hollender, A., Scand. (1962) J.Clin. Lab. Invest 14, 104; Raymond. S and Marumi.N. (1962) Anal. Biochem. 3, 23; Pastuska, G and Trinks, H. (1962) Chemiker Zig, 86, 135.

Dobici. F and Grassini. G. (1963) J. Chromatogr. 10, 98http://dx.doi.org/10.1016/S0021-9673(01)92278-2

Frache. R and Dadone. A. (1973) Chromatographia. 6, 430http://dx.doi.org/10.1007/BF02281022

Frache. R and Dadone. A. (1973) Chromatographia. 6, 266http://dx.doi.org/10.1007/BF02281022

Groulade. J, Fine. J.M and Ollivier. C. (1961) Nature, 191, 72http://dx.doi.org/10.1038/191072a0

Hollender. A, Scand. (1962) J. Clin. Lab. Invest, 14, 104

Honegger. C.G, Helv. (1961) Chim. Acta, 44, 173

Lurie. J. (1975) Handbook of Analytical Chemistry, Mir Publishers, Mascow p 30.

Makrova, T.P and Stapnov, A.V. (1972) Zh. Ana. Khim, 26(9), 1823; Sharma, S.D and Misra. S. (1991) J. Liq. Chromatogr. 14 (181), 1453

Makrova. T.P and Stapnov. A. V. (1971) Zh. Anal. Khim. 26(9), 1823

Martin. H.R. (1961) Experentia, 17, 235 http://dx.doi.org/10.1007/BF02160641

Moghissi. A. (1964) Anal. Chim. Acta. 80, 91http://dx.doi.org/10.1016/S0003-2670(00)88690-0

Murray. D.J and Fuerstnu. M.C. (1968) J. Inorg. Nucl. Chem., 30, 3325http://dx.doi.org/10.1016/0022-1902(68)80129-0

Pastuska. G and Trinks. H. (1961) Chemiker Ztg. 85, 535

Pastuska. G and Trinks. H. (1962) Chemiker Ztg. 86, 135

Qureshi. M, Kumar. R and Rathore. H.S. (1970) J. Chem. Soc. 272http://dx.doi.org/10.1039/j19700000272

Qureshi. M, Varshney. K.G and Fatima. N. (1978) Sepr. Sci and Technol., 13(4), 321.

Qureshi. M, Zehra. N, Nabi. S.A and Kumar.V. (1973) Talanta, 20, 609 http://dx.doi.org/10.1016/0039-9140(73)80111-0

Raymond. S and Masumi. N. (1962) Anal. Biochem. 3, 23http://dx.doi.org/10.1016/0003-2697(62)90040-4

Sharma. S.D and Gupta. Rachna. (2001) J. Ind. Chem. Soc. 78, 301

Sharma. S.D and Misra. S. (1991) J. Liq. Chromatogr. 14(8), 1453http://dx.doi.org/10.1080/01483919108049627

Sharma. S.D and Sharma. C. (2000) J. Planar Chromatogr. 13 93

Sharma. S.D and Sharma. S.C. (1999) J. Chromatogr. 841, 263http://dx.doi.org/10.1016/S0021-9673(99)00293-9

Sharma. S.D, Misra. S and Agarwal. R. (1995) Chem. Environ. Res. 4 (1 & 2), 111.

Sharma. S.D, Misra. S and Sharma.S.C. (1998) J. Ind. Chem. Soc. 75, 81

Sharma. S.D, Sharma. S.C and Sharma. C. (2001) J. Planar Chromatogr. 14, 16

Sharma. S.D, Sharma. S.C and Sharma.C. (1999) J. Planar Chromatogr, 12, 440

Shimizu. T, Tanake. T and Kobayashi. M, J. Planar Chromatogr., 8, 469

Shimizu. T, Tanake.T and Toyoshima .Y. (1994) J. Planar Chromatogr. 8, 152

Smithies. O. (1955) J .Biochem. 61, 629

Toube. H. (1952) Chem. Rev., 50, 69 http://dx.doi.org/10.1021/cr60155a003

Vahvaselko. E. (1962) Nature, 193, 474 http://dx.doi.org/10.1038/193474a0

Published
2015-03-30
How to Cite
Sd Sharma, & Mridul Gupta. (2015). Electrophoretic Study of d-Block Metal Ions on Plain and Tri-n-Butylamine (TBA) Impregnated Titanium (IV) Tungstate Layers. Journal of Chemistry, Environmental Sciences and Its Applications, 1(2), 97-109. https://doi.org/10.15415/jce.2015.12010
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Articles